Abstract
A tridentate hydrazone ligand N′-(2-hydroxy-4-diethylamino benzylidene)-3-methylbenzohydrazide (H2L), reacts with vanadyl sulfate in methanol to give a novel μ 2-oxo bridged dinuclear oxovanadium(V) complex, [V2O2(μ 2-O)L2]. The complex was characterized by physicochemical and spectroscopic methods. The crystal of the complex is triclinic with space group P–1, a = 11.349(2), b = 13.385(3), c = 13.644(2) Å, α = 90.377(2)°, β = 93.772(2)°, γ = 109.239(2)°, V = 1951.8(6) Å3, Z = 2. X-ray crystallography indicates that each V atom is in a distorted square pyramidal coordination. The two V atoms are bridged by one O atom, with a distance of 3.010(1) Å.
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