Abstract
Trimethylplatinum(IV) complexes of the type [PtMe 3X(Me 2NCH 2CH 2ER)] (X = Cl, Br, I; ER = SBu t, SC 6H 4Me-4, SPh, SePh, TePh) have been prepared and characterized by elemental analysis and NMR ( 1H and 13C) spectral data. The structure of [PtMe 3Br(Me 2NCH 2CH 2SC 6H 4Me-4)] has been determined by single-crystal X-ray diffraction. The central platinum atom is coordinated by three fac-methyl groups and nitrogen, sulphur and bromine atoms. The five-membered chelate ring PtNCCS is non-planar.
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