Abstract
The synthesis and characterization of the first soluble phthalocyaninatorhenium complexes with axial ligands nitride, N 3− or oxide, O 2− and ethoxide, EtO − soluble in common organic solvents are reported. Besides the monomer complexes ( t-Bu) 4PcReN ( 1) and ( t-Bu) 4 PcReO( OEt) ( 3) a dimeric μ-oxo compound [( t-Bu) 4 PcReO] 2 O ( 4) was also prepared. The complexes were characterized by NMR, UV/Vis, IR, MS and CV. The nitrido complex is compared with the already known unsubstituted compound PcReN ( 2).
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