Abstract
Herein it is reported how the overlap concentration (C*) can be used to overcome crosslinking due to diol impurities in commercial PEG, allowing for the synthesize of bottlebrush polymers with good control over molecular weight. Additionally, PEG-based bottlebrush networks are synthesized via ROMP, attaining high conversions with minimal sol fractions (<2%). The crystallinity and mechanical properties of these networks are then further altered by solvent swelling with phosphate buffer solution (PBS) and 1-ethyl-3-methylimidazolium ethyl sulfate/DCM cosolvents. The syntheses reported here highlight the potential of the bottlebrush network architecture for use in the rational design of new materials.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.