Abstract
AbstractStep heating melt polycondensation was adopted in the preparation of polyamides based on 1,16‐octadecane diacid and α,ω(CH2)2n diamines (n = 1–6). The structure was confirmed by various spectroscopic techniques (IR, Raman, 1H‐NMR, and 13C‐NMR). High molecular masses were obtained only in the presence of an excess of diamine and when the diamine possessed low volatility. The molecular masses were between (0.94 and 2.1) × 104 Da for all polyamides under consideration. An excellent correlation between size exclusion chromatography and 1H‐NMR data was demonstrated in the measurement of the degree of polymerization. The melting temperatures of the polyamides decreased from polyamide 12 18 to polyamide 2 18 as the amide density along the molecular chain declined. No significant variation was observed in the glass‐transition and decomposition temperatures of the polyamides that were obtained. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 1565–1571, 2005
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