Synthesis and characterization of metakaolin-based geopolymers doped with CRT waste glass for radiation shielding applications

Abstract

This study presents the influence of CRT glass on the gamma-ray interaction processes in metakaolin-based geopolymers. Four batches of G-CRT composites (namely, G, G-10CRT, G-20CRT, and G-30CRT, which represent geopolymer (G) samples doped with 0, 10, 20, and 30 wt% of CRT glass) were prepared using the cold hydrostatic press method. The mass attenuation coefficients of the prepared C-xCRT samples were computed using XCOM and FLUKA simulations for photons within the energy range of 15 keV–15 MeV. The density of the pristine geopolymer increased from about 1.86 g/cm3 to 2.09, 2.26, and 2.34 g/cm3 for G-10CRT, G-20CRT, and G-30CRT, respectively. The photon mass and linear attenuation coefficients of the geopolymers increased with CRT glass concentration. The half-value layer and mean free path were within the ranges 0.070–18.079 cm and 0.101–26.083 cm for G; 0.036–15.110 cm and 0.052–21.799 cm for G-10CRT; 0.024–13.197 cm and 0.014–19.039 cm for G-20CRT; and 0.018–12.074 and 0.026–17.419 cm for G-30CRT. The G-30CRT had the best gamma attenuating prowess in contrast to other G-xCRT. CRT-rich G-xCRT had a higher effective atomic number. For 10 mm thick geopolymer, the absorbed dose rates were 0.211 μR/h, 0.66 μR/h, 1.11 μR/h, and 1.55 μR/h for G, G-10CRT, G-20CRT, and G-30CRT, respectively, for 100 keV photons. The introduction of CRT glass into the geopolymer matrix improved their photon interaction cross-section. The geopolymers showed outstanding photon interaction ability compared to ordinary concrete and some shielding glasses at low photon energies. The CRT glass-doped geopolymer samples are useful for preparing radiation shielding concrete.