Synthesis and characterization of magnesium–carbon compounds for hydrogen storage

Abstract

Magnesium (Mg) and carbon (C) compounds were synthesized by ball-milling a mixture of Mg and different graphites with different crystallinities. The materials were characterized by X-ray diffraction, X-ray absorption spectroscopy, and X-ray total scattering techniques. Hydrogen storage properties were also investigated. In the case of the material using low-crystalline graphite, a Mg and C compound was formed as main phase, and its chemical bonding state was similar to that of magnesium carbide (Mg2C3). The hydrogen absorption reaction of the Mg–C compound occurred at around 400°C under 3MPa of hydrogen pressure to form magnesium hydride (MgH2) and the C–H bonds in the carbon material. The hydrogenated Mg–C material desorbed about 3.7mass% of hydrogen below 420°C with two processes, which were the decomposition of MgH2 and the subsequent reaction of the generated Mg and the C–H bonds. From the results, it is concluded that the Mg–C compound absorb and desorb about 3.7mass% of hydrogen below 420°C.