Synthesis and Characterization of Amorphous Selenium, Cadmium and Silver Selenide Thin Films on Polyamide-6

Abstract

Increasing photon absorption by capturing light is an important way to increase the efficiency of photovoltaic devices. In this regard, the small optical band gap (Eg) and high absorption coefficient of Se-containing thin nanofilms make them ideal for next generation photovoltaic devices based on selenides. Amorphous selenium was introduced into polyamide-6 (PA 6) via a chemical synthesis in a bath and the influence of the products of its reaction with Cd2+ and Ag+ ions on the film phase composition, topographic and optical properties were evaluated. AFM data have revealed that the surface roughness of the a-Se/PA 6 composite noticeably increases compared to that of unreacted PA 6. However, at later stages of film deposition, the roughness decreases, and the thin film becomes smoother and uniform. The incorporation of solid inorganic nanoparticles into flexible polyamide network causes chain stretching, which has been confirmed by ATR-FTIR spectroscopy data. The data of X-ray diffraction analysis, depending on the stage of synthesis, showed the crystalline composition of the film with peaks of Se8, CdSe, Ag2Se and Ag, which may explain the observed optical properties. The optical properties of the composites indicate a shift in the band gap from 4.46 eV for PA 6 to 2.23–1.64 eV upon the stepwise deposition of amorphous Se, CdSe and Ag2Se. Eg is conveniently located in the visible region of solar energy, making the obtained nanofilms ideal for solar energy harvesting.