Abstract
A novel spring-like organotin complex [(Ph 3Sn)(C 7H 5ClNO 2)] n· 3C 6H 6 (1), has been synthesized by treatment of 6-chloro-3-pyridineacetic acid bis(triphenyltin)oxide on the condition of reflux. The complex was characterized by elemental analysis, FT-IR, NMR ( 1H, 13C and 119Sn) spectroscopy, and X-ray crystallography diffraction analysis. The structure analyses reveals that complex 1 is an 1D infinite chain linked by intermolecular Sn–O bonds, in which the guest benzene molecules are established in the cavity of this helical chain; all the tin atoms of complex 1 are five-coordinated.
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