Abstract

Borazine-silicon-containing arylacetylene (PBZSA) resin was a novel organic inorganic hybrid polymer and prepared through condensation reaction among B,B’,B’’-trichloroborazine, dichlorosilane and arylacetylene Grignard reagent. The chemical structure of PBZSA resin was characterized by FT-IR and 1H NMR. The thermal stability and dielectric properties of cured PBZSA were investigated by TGA and broadband dielectric spectrometer. The results indicated that cured PBZSA showed high thermal stability with char yield up to 87.1% at 1000°C and at decompose temperature (Td5) 580°C, and low dielectric constant (2.8-2.9) and dielectric loss (<0.005).

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