Abstract
The reaction of Ag2SO4 and bpp (bpp = 1,3-bis(4-pyridyl)propane) in H2O afforded the complex [Ag2(bpp)2(SO4) · 6.5H2O·CH3OH]n, 1. The IR and TGA have been recorded and the structure has been determined. Crystal data for 1: Space group C2/c, a = 17.885(4), b = 25.230(6), c = 8.832(2) Å, β = 105.437(4)°. V = 3841(1) Å3, Z = 8 with final residuals R1 = 0.0710 and wR2 = 0.1620. The complex shows a three-dimensional supramoleclar structure constructed with two-dimensional infinite [Ag2(bpp)2]n sheetlike layers pillared by Ag-Ag interactions and Ag····O (SO4) interactions in the solid state.
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