Abstract
Assembly of isonicotinate acid (HL) and Ag(I) by a layer-separating diffusion method at ambient temperature gave rise to two novel structural coordination polymers with ligand unsupported Ag⋯Ag interactions, namely, [(Ag4L4)·H2O·0.5CH3OH]n (1) and [(Ag3L2)NO3]n (2). Compound 1 is the first example of double-layer architecture and features an alternative stacking mode with Ag⋯Ag interactions, π–π interactions and Ag⋯O interactions. The synthesis of compound 2 offered us an opportunity to study the role of counteranions in Ag⋯Ag interactions. Both compounds display intense room temperature photoluminescence in the solid state.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
