Syntheses, structures, and luminescent properties of lanthanide complexes with N,N′-bis(p-methoxyphenyl)-3-oxapentanediamide

Abstract

An amide-type acyclic polyether, N,N′-bis(p-methoxyphenyl)-3-oxapentanediamide (L), and its three lanthanide coordination compounds, [Ln(NO3)(L)2(H2O)2] · (NO3)2 [Ln = Pr (1), Nd (2), and Dy (3)], have been synthesized and characterized by elemental analysis, IR spectroscopy, thermal analysis, and X-ray diffraction. Single crystal X-ray structure analyses reveal that 1 and 2 have the same structure and crystallize in the monoclinic crystal system with C2/c space group. The coordination geometry around the central atom is a distorted bicapped square antiprism. Extensive intermolecular hydrogen bonds in 1 and 2 result in 3-D supramolecular networks. Complex 3 exhibits luminescence in the visible region upon excitation with UV-rays.