Syntheses, crystal structures, and catalytic properties of dioxomolybdenum(VI) complexes with hydrazone ligands

Abstract

Two new dioxomolybdenum(VI) complexes, [MoO2L1(CH3OH)] (1) and [MoO2L2(H2O)] (2), where L1 and L2 are dianionic form of N′-(2-hydroxy-3-methoxybenzylidene)-4methoxybenzohydrazide and N′-(2-hydroxy-3methoxybenzylidene)-2-hydroxybenzohydrazide, respectively, have been synthesized and structurally characterized by spectroscopic methods and single-crystal X-ray determination. The complexes are mononuclear molybdenum(VI) compounds. Mo in each complex is octahedral. The difference in the substituent groups in the benzohydrazides leads to coordination of different solvent molecules. Crystals of the complexes are stabilized by hydrogen bonds. The complexes are effective catalysts for sulfoxidation.