Abstract
A new complex [Tb(3-CNC6H4COO)3(H2O)2]n (I), where 3-CNC6H4COO is 3-cyanobenzoate, has been synthesized, and the crystal structure was determined by X-ray crystallography. The result shows that 1,3-dicyanobenzene was hydrolyzed to give 3-cyanobenzoate under the hydrothermal conditions. Complex I forms a one-dimensional coordination polymer. Complex I crystallizes in the triclinic system, space group P\(\bar 1\), with lattice parameters a = 9.3749(9), b = 11.4943(10), c = 12.7024(11) A, α = 65.563(4)°, β = 73.788(5)°, γ = 86.757(5)°, V = 1193.89(19) A3, Z = 2, ρcalcd = 1.757 mg m−3. The photophysical property of I has been studied by the excitation and emission spectra, which exhibit strong green emission.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
