Syntheses and redox behavior of novel cyclic hosts having multiple redox centers of NAD + analogue

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A new series of cyclophanes having 3,5-dicarbamoylpyridinium moieties were synthesized by the stepwise reactions starting from half protected compounds. The one-eletron reduction potentials of these new cyclophane type NAD + analogues are determined by the cyclic voltammetric method. The results indicate that the reduction potentials are primarily regulated by the through-bond mechanism.