Abstract
New iridium porphyrin complexes (I-V) have been prepared by the reactions of octaethylporphyrin (OEPH 2) or N-methyloctaethylporphyrin (N-Me·OEPH) with μ-dichloro-hexacarbonyl-diiridium(I) ([Ir(CO) 3Cl] 2) or μ-dichlorobis[π-cyclooctadiene-(1,5)]-diiridium(I) ([Ir(COD)Cl] 2). Hydrido- and organo-iridium(III)OEP complexes (VI-XII) have been synthesized by various methods and characterized on the basis of spectroscopic measurements.
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