Abstract
Synthesis and Crystal Structure of [Na3(H2O)6,5(EtOH)][PhSnS3] · 3 EtOH Ph4Sn4S6 reacts with Na2S · 5 H2O in aqueous acetone to form Na3[PhSnS3]. Recrystallization of the crude product from ethanol leads to colourless needles of [Na3(H2O)6,5(EtOH)][PhSnS3] · 3 EtOH 1. The crystal structure of 1 was determined by X-ray diffraction. 1 consists of [PhSnS3]3– anions and sodium cations which are coordinated by water, ethanol and sulfur atoms of the [PhSnS3]3– anions. The [PhSnS3]3– anion contains a tin atom which is coordinated nearly tetrahedrally by a phenyl group and three sulfur atoms. The Sn–S bonds are 237,4(2)–238,4(2) pm.
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