Synergistic modification of bentonite by acid activation and hydroxyl iron pillaring for enhanced dye adsorption capacity.

Abstract

Despite the fact of natural abundance, low cost and environmental friendliness, the far-from-sufficient adsorption capacity of natural bentonite (BT) has limited such a promising application to remove dye pollutants. In this paper, we proposed a facile modification strategy to enhance adsorption performance of bentonite utilizing synergistic acid activation and hydroxyl iron pillaring, by which the adsorbent (abbreviated as S-Fe-BT) exhibited the highest adsorption capacity (246.06 mg/g) and a high rapid adsorption rate for a typical organic dye, Rhodamine B (RhB). This could be ascribed to the increased interlayer spacing, the increased specific surface area, and the optimized OH/Fe ratio after the synthetic modification of the pristine BT. The adsorption behavior of RhB onto S-Fe-BT was well described by the pseudo-second-order kinetic model, indicating a chemical-adsorption-controlled process. Furthermore, its adsorption isotherm matched well with the Langmuir model due to a monolayer adsorption process. This paper opens a promising direction to remove the dye pollution using low cost bentonite adsorbents treated by such a convenient modification strategy.