Synergistic effect between POSS and fumed silica on thermal stabilities and mechanical properties of room temperature vulcanized (RTV) silicone rubbers

Abstract

In this paper, both divinyl-hexa[(trimethoxysilyl)ethyl]-POSS (DVPS) and fumed silica were firstly introduced into polydimethylsiloxane (PDMS) system using as the cross-linker and the reinforcing filler respectively. And a series of novel RTV silicone rubbers synergistically enhanced by DVPS and fumed silica were prepared. The cross-linked networks in the novel RTV silicone rubbers have been studied by attenuated total reflection infrared spectroscopy, and the dispersions of POSS and fumed silica in these novel RTV silicone rubbers have been observed by means of scanning electron microscope (SEM). And thermal stabilities, thermo-oxidative stabilities and mechanical properties of these novel RTV silicone rubbers were studied by means of thermal gravimetric analysis and universal tensile testing machine, respectively. From the obtained results, it was found that synergistic effect between POSS-rich areas and fumed silica on thermal stability and mechanical property of RTV silicone rubber indeed existed. And the experimental results also exhibited that the thermal stabilities and mechanical properties of the novel RTV silicone rubbers were far better than those of the reference materials (DVPR and MTFR). The striking enhancements in thermal properties and improvements on mechanical properties of novel RTV silicone rubbers were likely attributed to the synergistic effect between POSS-rich domains and fumed silica. Meanwhile, it was found that the mechanical properties of RTV silicone rubbers prepared with a given amount of POSS cross-linker were enhanced with the increment of the loading amount of fumed silica.