Synergistic Ag/g-C3N4 H2O2 System for Photocatalytic Degradation of Azo Dyes.

Abstract

Graphitic carbon nitride (g-C3N4), known for being nontoxic, highly stable, and environmentally friendly, is extensively used in photocatalytic degradation technologies. Silver nanoparticles effectively capture the photogenerated electrons in g-C3N4, enhancing the photocatalytic efficiency. This study primarily focused on synthesizing graphitic carbon nitride via thermal polymerization and depositing noble metal silver onto g-C3N4 through photoreduction. Methyl orange (MO) and methylene blue (MB) were targeted as the pollutants in the photocatalytic experiments under visible light in conjunction with a H2O2 system. The characteristics peaks, structure, and morphology were analyzed using Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and scanning electron microscopy (SEM). g-C3N4 loaded with 6% Ag exhibited superior photocatalytic performance; the photocatalytic fraction of the degraded materials of the MO and MB solutions reached 100% within 70 and 80 min, respectively, upon adding 1 mL and 2 mL of H2O2. ·OH and ·O2- were the primary active free radicals in the dye degradation process within the synergistic system. Stability tests also demonstrated that the photocatalyst maintained good reusability under the synergistic system.