Syndioselective coordination polymerization of unmasked polar methoxystyrenes using a pyridenylmethylene fluorenyl yttrium precursor.

Abstract

Unprecedented coordination-insertion polymerizations of polar methoxyl substituted styrene derivatives, in despite of the position of the substituent, have been achieved using a pyridyl methylene fluorenyl yttrium bis(alkyl) precursor with high activity to give polar polystyrenes of high molecular weight and perfect syndiotacticity.