Abstract
Cross-coupling of benzylic carbonates with heteroarylboronic acids successfully proceeded in the presence of the palladium catalyst that was generated in situ from [Pd(η 3 -C 3 H 5 )Cl] 2 and a chelate bisphosphine DPPPent. Various heteroarylboronic acids were applicable to the catalytic cross-coupling, giving the desired benzylated heteroaromatics in high yields.
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