Abstract
Nanocrystalline pyrochlore materials have been investigated for their enhanced radiation tolerance as ceramic nuclear waste hosts. In this work, we study the thermodynamic driving force of nano-scale materials for radiation resistance. The size dependent thermodynamic properties of a series of Y2Ti2O7 nanoparticles were investigated. Samples were synthesized by a sol-gel method and characterized by synchrotron X-ray diffraction, BET analysis, and thermogravimetric analysis. The surface and interface enthalpies of Y2Ti2O7 were determined by high temperature oxide melt drop solution calorimetry to be 4.07 J m-2 and 3.04 J m-2, respectively. The experimentally obtained surface energy is in good agreement with computationally derived average surface energies for yttrium and other rare-earth titanate pyrochlores. Theoretical links between nanoparticle stability, surface energy, and radiation resistance of pyrochlore materials were then explored.
Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
