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Abstract
We report in this work, experimental surface tensions for binary mixtures of isomeric chlorobutanes with butyl ethyl ether or diisopropyl ether from T=283.15K to 303.15K measured with a drop volume tensiometer. The surface tension data have been correlated with a Redlich–Kister type equation. More information about the surface behaviour can be obtained combining these results with previously reported VLE measurements to calculate the excess surface composition of ether in the mixture. Finally, the results have been compared to the predictions obtained using a group contribution method.
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