Abstract
The uptake of NO3 radicals on the surface of coatings prepared from the individual salts of NaI and NaBr dehydrates, hexahydrates of MgBr2, and MgCl2 and NaI · 2H2O/NaBr · 2H2O and MgBr2 · 6H2O/MgCl2 · 6H2O binary salts at various mole fractions of the doping salts, NaI · 2H2O and MgBr2 · 6H2O in the initial aqueous solution was measured in a flow reactor by kinetic mass spectrometry. The dependences of the rates of the consumption of the reactant and of the formation of the products on the mole fraction of the doping salt made it possible to determine a quantitative relationship between the surface density of the doping salt and its mole fraction in the initial solution. A joint analysis of these dependences and the previously obtained data led to the conclusion that the deliquescence of the studied individual salts produces the predominant effect on the ratio between their surface densities.
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