Abstract

Surface resonance x-ray scattering, sensitive to the monolayer-level change of an oxidation state of a buried interface, is used for the investigation of electrochemical oxidation of Pt(111) single crystal surface. The strongly $\mathbf{Q}$-dependent energy scans through the ${L}_{\mathrm{III}}$ resonance energy of Pt atoms were accounted for by a large increase of the electron binding energy of the surface atoms as a result of surface anodic oxidation.

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