Abstract

Inhibition of corrosion of carbon steel in dam water by hexanesulphonic acid as its sodium salt C6H13SO3Na (SHXS) in the absence and presence of a bivalent cation zinc ion (Zn2þ) has been investigated using weight loss method. Results of weight loss method indicate that inhibition efficiency (IE) increased with increase of inhibitor concentration. Polarization study reveals that SHXS-Zn2+system controls the cathodic reaction predominantly. AC impedance spectra reveal that a protective film is formed on the metal surface. The nature of the metal surface has been analysed by Fourier Transform Infrared Spectroscopy (FTIR) and Atomic Force Microscopy (AFM).

Highlights

  • Corrosion is a naturally occurring phenomenon which deteriorates a metallic material or its properties because of a reaction with its environment

  • This paper focuses on the inhibition efficiency (IE) of hexanesulphonic acid as its sodium salt (SHXS) in controlling corrosion of carbon steel immersed in dam water in the absence and presence of Zn2+

  • A synergistic effect exists between SHXS and Zn2+

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Summary

Introduction

Corrosion is a naturally occurring phenomenon which deteriorates a metallic material or its properties because of a reaction with its environment. Corrosion can cause dangerous and expensive damage to everything from pipelines, bridges, and public buildings to vehicles, water, and wastewater systems, and even home appliances. It is one of the most serious problems in the oil and gas industry. Studies report that the adsorption of organic inhibitors mainly depends on some physicochemical properties of the molecule, related to its functional groups, to the possible steric effects and electronic density of donor atoms: adsorption is supposed to depend on the possible interaction of P-orbitals of the inhibitor with d-orbitals of the surface atoms, which induce greater adsorption of the inhibitor molecules onto the surface of carbon steel, leading to the formation of a corrosion protective film [5]

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