Surface Modification of Poly(tetrafluoroethylene) Films by Plasma Pre-Activation and Plasma Polymerization of Glycidyl Methacrylate

Abstract

Surface modification of poly(tetrafuoroethylene) (PTFE) film by plasma polymerzation and deposition of glycidyl methacrylate (GMA), in the presence and absence of Ar or O2 plasma pre-activation, was carried out to enhance the adhesion with polyimides (PI) film in the presence of an epoxy adhesive. For deposition carried out at low RF power, a high epoxide concentration was preserved in the plasma-polymerized GMA (pp-GMA) layer on PTFE (pp-GMA-PTFE). However, high adhesion strength of the PI/pp-GMA-PTFE laminate was obtained only in the presence of O2 plasma pre-activation of the PTFE substrates prior to plasma polymerization and deposition of GMA. In the absence of any plasma pre-activation or in the presence of Ar plasma pre-activation, the deposited pp-GMA layer on the PTFE surface could be readily removed by solvent extraction. The adhesion enhancement of the PI/pp-GMA-PTFE laminates in the presence of O2 plasma pre-activation was attributed to the preservation of the epoxide functional groups in the pp-GMA layer, the curing of the GMA chains into the matrix of the epoxy adhesive, and the covalent bonding of the pp-GMA layer on the PTFE surface.