Surface functionalization of polytetrafluoroethylene membrane by polydopamine and quaternary ammonium compound for fouling mitigation in membrane distillation of secondary effluent

Abstract

Considering the worldwide water scarcity issue, membrane distillation (MD) offers a promising solution for producing reclaimed water from secondary effluent generated by municipal wastewater treatment plants. However, prolonged operation of MD systems can result in membrane fouling, which impairs separation efficiency and shortens the membrane's lifespan. To overcome these challenges, novel surface-modified polytetrafluoroethylene (PTFE) membranes have been developed through a combination of polydopamine deposition and quaternary ammonium compound (QAC) grafting (named as PDQ membranes). The objectives of this preparation are to reduce the membrane hydrophobicity, impart anti-adhesive and bactericidal properties, and improve water permeability and antifouling performance in the MD system. In particular, the membrane coated by a QAC solution with the concentration of 40 mM (named as M3 membrane), achieved a flux of 47.0 LMH, surpassing the original PTFE membrane by 11.4%. During the long-term direct contact membrane distillation operation with the secondary effluent, the M3 membrane exhibited significantly superior antifouling capability than the PTFE membrane. Undergoing three runs of the MD process, the flux reduction of M3 was only 38.1%, whereas the flux of original PTFE membrane experienced a 71.4% decline. The PDQ membranes were also capable of providing stable distillate quality (over 40 h). Notably, the M3 demonstrated a high rejection capability, with an impressive removal efficiency of 96.9% for low molecular weight organics and 92.5% for humus-like substances. Additionally, the PDQ membrane exhibited good anti-bioadhesion and bactericidal properties. This study highlights the promising application potential of the PDQ membrane for fouling mitigation in water and wastewater treatment.