Abstract
Monolayer transition metal dichalcogenides MX2 (M = Mo, W; X = S) exhibit remarkable electronic and optical properties, making them candidates for application within flexible nano-optoelectronics. The ability to achieve a high optical signal, while quantitatively monitoring strain in real-time is the key requirement for applications in flexible sensing and photonics devices. Surface-enhanced Raman scattering (SERS) allows us to achieve both simultaneously. However, the SERS depends crucially on the size and shape of the metallic nanoparticles (NPs), which have a large impact on its detection sensitivity. Here, we investigated the SERS of monolayer MX2, with particular attention paid to the effect of the distribution of the metallic NPs. We show that the SERS depends crucially on the distribution of the metallic NPs and also the phonon mode of the MX2. Moreover, strong coupling between MX2 and metallic NPs, through surface plasmon excitation, results in splitting of the and modes and an additional peak becomes apparent. For a WS2-Ag system the intensity of the additional peak increases exponentially with local strain, which opens another interesting window to quantitatively measure the local strain using SERS. Our experimental study may be useful for the application of monolayer MX2 in flexible nano-optoelectronics.
Highlights
Known to produce enhancements through surface plasmon resonances[34,35,36]
We investigated the Surface-enhanced Raman scattering (SERS) of monolayer MX2, with particular attention paid to the effect of the distribution of the metallic NPs
The chemical composition of the WO3 was investigated by X-Ray photoelectron spectroscopy (XPS)
Summary
By growing Ag NPs on the top of monolayer MoS2, an increase in the intensity of the Raman active modes is observed. To further investigate the impact of Ag NP distribution on the SERS signal, Fig. 4a shows Raman spectra of monolayer WS2 with different nominal thicknesses of Ag NPs on top. 4obu)t-aonfd-paldandeitiAo1n′ (aΓl p) emaokds eshs,otwheuepnahta4n0c5emanedn4t 3fa2c ctmor−i1s less sensitive to the nominal thickness of (Fig. 4c) It was shown by Wang et al that due to strong surface plasmon excitation, the Raman signal at the boundary of metal-WS2 is dominated by local strain and the out-of-planeA1′ (Γ) mode is split[36]. The intensity of the additional peak increases exponentially with local strain, which opens another interesting window into quantitatively measuring the local strain through SERS
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