Abstract

AbstractA polysiloxane–poly(methyl methacrylate) (PMMA) graft copolymer was prepared by hydrosilylation reaction between a SiH containing polysiloxane and an allyl‐terminated PMMA. The obtained graft copolymer was blended with PMMA homopolymer. The addition of only 0.01 wt % of graft copolymer was sufficient to make PMMA surfaces hydrophobic. In acetone–cyclohexane mixed solvent, the graft copolymer formed a polymeric micelle by the aggregation of PMMA branches.

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