Abstract
The syntheses of vanadium complexes with tridentate PNP pincer ligands based on 2,6-diaminopyridine of the type [(PNP)VCl3] are reported. All compounds reveal distorted octahedral metal coordination geometry with three meridionally placed donor atoms of the PNP ligand and one chlorine atom occupying the equatorial plane of the octahedron. The axial positions are occupied by the other two chloride ligands. Complexes [(PNP)VCl3] were obtained as different solvates displaying hydrogen bonds between the PNP ligands and solvent molecules. The NH spacer groups in the PNP ligands are responsible for the establishment of hydrogen bonds that determines the solid state supramolecular architectures.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
