Abstract

Copper sulfide (CuS) was grown on the carbon cloth (CC) utilizing the traditional hydrothermal method. The role of different reaction time of 5 h, 10 h, and 15 h (C15) were investigated with fixed reaction time of 150 °C. XRD confirmed the growth of pure CuS on CC. Macroscopic changes in morphology were observed with increasing the reaction time and C15 showed ∼3.08 μm diameter of CuS microflowers with ∼ 34.68 nm thickness of nanosheets embedded in the microflowers. C15 showed a lowest bandgap of 1.8 eV with high copper content of 34 % and the copper content increases fast electron movement and maintains structural stability. The supercapacitor behavior was investigated in 1 M Mg(NO3)2 aqueous electrolyte and C15 demonstrated the highest specific capacitance of 83.70 F/g at 5 mV/s. An aqueous symmetric electrode made with C15 displays 149 F/g specific capacitance and 87.2 % retention at 1 A/g for 1000 cycles.

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