Abstract
The compounds RSO2NHOH, (RSO2)2NOH, and RSO2NH2(R = Ph or p-MeC6H4) are all converted by nitrosyl chloride into RSO2Cl, but (RSO2)2NOSO2R and (RSO2)2NH are unaffected; RSO2NHOH, (RSO2)2NOH, and (RSO2)2NOSO2R all initiate free-radical halogenation by dichlorine and dibromine, but not by di-iodine, of benzene and cyclohexane. Oxidatron of PhSO2NHOH by a range of oxidants yields PhSO2Cl, PhSO3H, or (PhSO2)2NOSO2Ph, but not PhSO2NO. The compound p-MeC6H4SO2Na is converted by NOCl into p-MeC6H4SO2Cl rather than to p-MeC6H4SO2NO; (p-MeC6H4SO2)2NH is inert to a wide range of oxidants.
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