Abstract
We have investigated thep-toluenesulfonic peracid ( 2) generated in situ in the oxidation of different types of compounds containing nitrogen and/or sulfur. The sulfonic peracid 2 shows a remarkable chemoselectivity characterized by a preferred oxidation of sulfides to the sulfones in the presence of amines or olefins and a strong dependence on the nature of the amine in the competitive oxidation of olefins and amines. p-Toluenesulfonic Peracid ( 2) generated in situ was applied for the chemoselective oxidation of substrates containing C-C double bonds and/or N- and S-functionalities, e. g. [Display omitted]
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