Sulfonated Poly(2,6-dimethyl-1,4-phenylene ether)-Modified Mixed-Matrix Bifunctional Polyelectrolyte Membranes for Long-Run Anthrarufin-Based Redox Flow Batteries.

Abstract

The resurgence in designing polyelectrolyte membrane (PEM) materials has propound grid-scale electrochemical energy storage devices. Herein, we report on studies corroborating the synergistic influence of ionic domain microstructure modification and intercalation of telechelic bis-piperidinium-functionalized graphene oxide (GO) to fabricate stable bifunctional membranes from sulfonated poly(2,6-dimethyl-1,4-phenylene ether) (sPPE) for efficient anthrarufin-based alkaline redox flow batteries. A critically long-lasting quest on alkaline stability and -OH conductivity dilemma in hydrocarbon-based PEMs is meticulously resolved via a bifunctional ion-conducting matrix. Preferential studies on hydrophilic domain distribution in sPPE suggest that, with high microphase homogeneity, higher specific capacity retentions are achievable during galvanostatic charge-discharge (GCD) analysis. Moreover, the low-capacity issues were overcome by improving the redoxolyte-membrane interface affinities incorporating bis-piperidinium-bearing graphene oxide (bis-QGO). Consequently, at 1.0 and 2.0 wt % intercalation of bis-QGO, the bifunctional polyelectrolyte membranes (BFPMs) impart lowest overpotentials of 93 mV (for BFPM-1.0) and ∼100 mV (for BFPM-2.0) which are ∼43 and 40% lower than that of Nafion-117 (i.e., ∼164 mV). Furthermore, the efficiency of BFPMs, viz., the Coulombic, voltage, and energy efficiencies, was ∼95-98%, ∼85%, and ≥80% at 20 mA cm-2, respectively. In long-cycling operations, the GCD profile evidenced ∼99% efficiency retention over 450 cycles and illustrated reproducible rate capability. Finally, the polarization studies of BFPMs revealed ∼54% higher peak power density (87.5 mW cm-2) delivery than Nafion-117 (∼57 mW cm-2). We believe that this strategic designing approach could offer newer and simple avenues to avail high-performance BFPMs at low intercalation loads for alkaline electrochemical energy storage and related applications.