Abstract

AbstractDecade advances of sulfinic acids (2010‐2021) were summarized via four categories by mechanisms: (1) sulfonyl radicals (2) RS radicals; (3) electrophilic intermediates; (4) nucleophilic S‐reagents. Their reactions with alkenes, alkynes, propiolic acids, cinnamic acids, allenes, ynones, azides, enynals, aldehydes, ketones, o‐aryl isocyanides, arenes, quinoline N‐oxides, disulfides, diselenides, thiophenol, P(O)‐H compounds, nitriles, alcohols, nitroso benzenes and dizo compounds will be discussed.

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