Abstract
Decade advances of sodium sulfinates in radical reactions (2010–2021) were summarized via three categories by mechanisms: (1) sulfonyl radicals (2) RS radicals; (3) trifluoromethyl radicals. Their reactions with arenes, quinoline N-oxides, aryl halides, ethers, alkenes and alkynes, enamides, cinnamic acids, propiolic acids, nitrostyrenes, 2-methylquinolines, enamines, ketones, diazoium salts, isocyanides, amines, NH-sulfoximines or Selectfluor will be discussed.
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