Abstract
Kinetics of chemiluminescence reactions of 2-methyl-6-phenylimidazo[1,2- a]pyrazin-3(7 H)-one ( 1c , Cypridina luciferin analogue) and substituent effects of the 6-aryl group of derivatives 1 strongly suggest that the rate-determining step is a single electron transfer from an anion derived from 1 to a triplet molecular oxygen (O 2) in the oxygenation process.
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