Abstract
The (6 R*,9 S*,11 S*) and (22 S*,23 R*,27 R*,31 R*) stereochemistry, respectively, of the tetrahydropyranyl and spiroacetal moieties in bistramide A ( 1 ) have been established by stereoselective syntheses and high field NMR comparisons. Routes to the γ-amino acid moiety are outlined.
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