Abstract
Abstract SF 2 radicals were generated by using a pulsed dc discharge in a mixture of SF 6 /Ar. The (2+1) resonance-enhanced multiphoton ionization (REMPI) spectroscopy of SF 2 radical was observed between 320 and 365 nm. The analysis shows that the observed spectra can be assigned as the resonant excitation of the SF 2 radical (the 4s Rydberg state and C state). The spectroscopic parameters ω 1 ′ and ω 2 ′ were obtained. We also clarified the dissociative characteristics of the C state and inferred the mechanism of dissociation.
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