Study on the properties of multi-walled carbon nanotubes reinforced poly (vinyl alcohol) composites

Abstract

Nanocomposite films based on polyvinyl alcohol(PVA) and multi-walled carbon nanotubes (MWCNTs) at different weight ratios (i.e.0.0,0.5, 1.0,1.5, 2.0 wt%), were prepared by dispersion techniques. Cationic geminisurfactant and its monomeric form (0.01 wt%) were used as dispersants to achieve homogeneous and stable dispersionof CNTs in water and subsequent PVA/CNTs nanocomposites. Surface charge of CNTs in aqueous suspension with addition of the used dispersants were investigated by measuring its zeta potential. The structural and interaction studies have been analyzed from X-ray diffraction (XRD) and Raman spectroscopy. The effect of the used surfactantson the separation and distribution of CNTs in PVA matrix was studied by visual characterization based on scanning electron microscopy (SEM). Thermal, mechanical and electrical properties of the prepared nanocomposites were evaluated and the results were discussed in relation with the CNTs content and surfactant type as dispersant. Surfactant effect improved the dispersion homogeneity of CNTs (at 1.0 wt%) within the polymer matrix. The physical interaction between. CNTs and PVA macromolecular chains resulting in nanocomposites with largely enhanced properties compared to those prepared with higher filler loading by avoiding the agglomeration phenomenon of nanotubes. On the other hand, the addition of CNTs by content up to 2 wt%, increases the electrical conductivity to be 10−6 Scm−1 at room temperature which highly recommends such composites to be used in electrostatic dissipation applications upon using gemini surfactant. Furthermore, useful nanosized capacitor structure based onnanocomposites containing its monomeric form, characterized by high permittivity and low dielectric loss, can be formed.