Abstract

In this paper, Polyethylene oxide (PEO) is used as the main material to prepare PEO–LiClO4, a polymer electrolyte packaging material. The complexation mechanism of PEO–LiClO4 was studied by fourier transform infrared (FT-IR) spectra. Finally, the bonding of PEO–LiClO4 with Al was completed by anodic bonding method. Secondly, the bonding mechanism of PEO–LiClO4 and Al was revealed by FT-IR and energy dispersive spectrum analysis. The results show that in a certain range, the more lithium salt content, the more Li+ number of ether oxygen coordination in the molecular chain of LiClO4 and PEO, the higher the degree of complexation; under the action of strong electrostatic field, the ion-coordination exchange of PEO–LiClO4 and Al at the bonding interface by ion diffusion is the direct reason for the two to achieve bonding.

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