Abstract
In order to provide paleofluid evidence of hydrocarbon accumulation periods in the Amu Darya Right Bank Block, microexperiments and simulations related to the Middle-Upper Jurassic Callovian-Oxfordian carbonate reservoirs were performed. On the basis of petrographic observation, the diagenetic stages were divided by cathodoluminescence, and the entrapment stages of fluid inclusions were divided by laser Raman experiment and UV epifluorescence. The hydrocarbon generation (expulsion) curve and burial (thermal) history curve of source rocks were simulated by using real drilling data coupled with geochemical parameters of source rocks, such as total organic carbon (TOC) and vitrinite reflectance ( R o ). The above results were integrated with microthermometry of fluid inclusions by inference the timing of hydrocarbon migration into the carbonate reservoirs. The horizon-flattening technique was used to process the measured seismic profile and restore the structural evolution profile. Four diagenetic periods and three hydrocarbon accumulation periods were identified. (i) For Syntaxial stage, the fluid captured by the overgrowing cement around particles is mainly seawater; (ii) for (Early) Mesogenetic burial stage, the calcite cements began to capture hydrocarbon fluids and show yellow fluorescence under UV illumination; (iii) for (Late) Mesogenetic burial stage, two sets of cleavage fissures developed in massive calcite cements, and oil inclusions with green fluorescence were entrapped in the crystal; (iv) for Telogenetic burial stage, blue fluorescent inclusions along with hydrocarbon gas inclusions developed in dully luminescent calcite veins. Based on the accurate division of hydrocarbon migration and charging stages, combined with the structural evolution history of the traps, the hydrocarbon accumulation model was established. Because two of the three sets of source rocks are of marine origin, resulting in the lack of vitrinite in the kerogen of those source rocks, there may be some deviation between the measured value of R o and the real value. Some systematic errors may occur in the thermal history and hydrocarbon generation (expulsion) history of the two sets of source rocks. Due to the limitations of seismic horizon-flattening technique—such as the inability to accurately recover the inclined strata thickness and horizontal expansion of strata—the final shape of the evolution process of structural profile may also deviate from the real state in geological history. The accumulation model established in this study was based upon the fluid inclusion experiments, which can effectively characterize the forming process of large condensate gas reservoirs in the Amu Darya Right Bank Block and quantify the timing of hydrocarbon charging. However, the hydrocarbon migration and accumulation model does not take the oil-source correlation into account, but only the relationship between the mature state of source rocks and the timing of hydrocarbon charging into the reservoirs. Subsequent research needs to conduct refined oil-source correlation to reveal the relationship between gas, condensate, source rocks, and recently discovered crude oil and more strictly constrain and modify the accumulation model, so as to finally disclose the origin of the crude oil and oil reservoir forming process in the Amu Darya Right Bank Block, evaluate the future exploration potential, and point out the direction of various hydrocarbon resources (condensate gas and crude oil).
Highlights
The Amu Darya Right Bank Block project is the largest one for natural gas cooperation between China and Turkmenistan
In 2020, some reservoirs that mainly produce normal crude oil were discovered around large condensate gas reservoirs which produce condensate oil, indicating that we have not fully understood the regular pattern of hydrocarbon accumulation in the ADRBB
We conduct various microscopic experiments such as cathodoluminescence of the Middle-Upper Jurassic Callovian-Oxfordian carbonate reservoirs in the ADRRB and the microthermometry and Raman spectrum of fluid inclusions of the J2k-J3o reservoirs
Summary
The Amu Darya Right Bank Block (the block is denoted by ADRBB in the following text) project is the largest one for natural gas cooperation between China and Turkmenistan. Based on the hydrocarbon generation (expulsion) history of source rocks and the structural evolution history of the strata, the forming process of hydrocarbon reservoirs is restored (Figure 1). Hydrocarbon charging and reservoir diagenesis are simultaneous geological processes in the petroleum system, and the constructive and destructive actions of diagenesis on the reservoir determine whether there is enough space to accommodate oil and gas. Destructive diagenesis includes compaction, cementation, stylolitization, and recrystallization Other diagenesis, such as hydrocarbon generation overpressure in shale, belongs to positive diagenesis. The microthermometry and Raman spectrum of secondary fluid inclusions can provide direct data for the timing of the entrapment, and the structural recovery from real data of traps can show the formation process of hydrocarbon reservoirs and help delimit the migration pathways of oil and gas [8]
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