Study of the v1,v3 bands of120SnH 4 : Part II--semiclassical qualitative analysis: critical phenomena and diabolic points

Abstract

The qualitative modifications of the rovibrational energy-level structure under rotational excitation are studied for the (nu) <SUB>1</SUB>, (nu) <SUB>3</SUB> bands of <SUP>120</SUP>SnH<SUB>4</SUB>. Two types of qualitative changes are shown to exist: the critical phenomena corresponding to the modification of the cluster structure and the so-called diabolic points associated with the redistribution of energy levels between different branches as the rotational quantum number increases. A simple model interpretation of energy-level redistribution is given to show that such a phenomenon is typical for tetrahedral molecules.