Abstract
Tetraalkylammonium halides decelerate the reaction of aluminium in aqueous NaOH solutions. Their effect depends on the alkyl group, on the anion, and on their concentration; and it is additive with the effect of Ca2+ ions. The inhibition effects under study and the shift of the stationary potentials to more anodic values are shown to be related with the influence on the cathodic process, resulting in a retardation of the whole corrosion process.
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