Abstract

A study has been made of the press moulding of a polyphenylene prepolymer based on 4,4′-diacetyldiphenyl oxide. It was found that two main processes take place during formation of the phenylene type polymer structure. The reaction taking place at 250–300° results in transformation of ketal and acetyl endgroups into dypnone fragments leading to formation of polymer with a partially crosslinked structure. Further transformations of acetyl and dypnone groups take place during high temperature moulding (450°) through cyclopolycondensation, as well as dehydration and diphenylation processes resulting in the formation of polyphenylene type three-dimensional structures.

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