Abstract

Converting microwaves energy into electric current has been studied through co-precipitation and sintering process on the semiconductor material. Most of the application of these methods still had a challenge of lowering the resistivity value of semiconductor material. Some researches indicated by adding molten salt into semiconductor material can reduce the resistivity value. In this study, the synthesis process by combining the co-precipitation and sintering method of transition metal (titanium and copper) and alkali metal (Sodium) shown an improvement in lowering resistivity problems. Composition ratio, temperature, and distance of radiation were the variable of measurement in this research. Three semiconductor materials NaxCuyTiz were synthesized by using 60 ml of hydrochloric acid (HCl) and 80 ml of ammonium hydroxide (NH4OH) as a reagent in co-precipitation method and sintering at temperature 500°C. An Olympus microscope was used to analyze the microstructures of all three materials. Fractions x, y, and z in the materials were determined by analysis of X-ray spectrograph model 2501. The resistivity values of three materials, namely as Na0.52Cu0.37Ti0.11, Na0.26Cu0.39Ti0.35, and Na0.26Cu0.67Ti0.07 were obtained by varying the temperature of measurement. The microwave radiation was measured by observing the output voltage and current along with the radiation at a variable distance (60, 90, 10, 150, 180, and 210 cm) through the semiconductor material. The experiment showed that material Na0.52Cu0.37Ti0.11 had low resistivity and small bandgap energy as 0.875 eV and able to convert microwave energy from 1.624 × 10−24 Watt to 9.137 Watt at 60 cm of microwaves radiation distance.

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