Abstract

Densities and speed of sound have been reported for the binary mixtures containing benzyl amine and cyclic ethers (1,3-dioxolane, 1,4-dioxane, THF, 2-MTHF) at three different temperatures ( T = 303.15 K, 308.15 K and 313.15 K) and at atmospheric pressure. The experimental data of densities and speed of sound has been further utilised to calculate excess molar volume ( V m E ) and excess molar isentropic compression ( K S . m E ). The excess properties have been fitted to Redlich–Kister equation. Further, theoretical results have also been discussed by using Prigogine–Flory–Patterson (PFP) theory, Intermolecular free length theory (FLT) and collision frequency theory (CFT). FTIR studies have also been added to justify the results.

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